Vapor–Liquid Equilibria of the Aqueous and Organic Mixtures Composed of Dipropylene Glycol Methyl Ether, Dipropylene Glycol n-Butyl Ether, and Propylene Glycol n-Butyl Ether. Part II: Modeling Based on the NRTL-PR Model
نویسندگان
چکیده
Further to Part I of our study glycol ether binary mixtures [Dimitrov, O.; Ind. Eng. Chem. Res. 2021, 60, 9602−9612], this second part is concentrated around the vapor–liquid equilibrium (VLE) modeling involving three ethers previously studied experimentally. The authors propose use NRTL-PR model for representation these nonideal mixtures. main difficulties related very low vapor pressures and approach cope with them are highlighted. unknown critical parameters DPM, DPnB, PnB were determined using robust group contribution methods. However, experimental values have never been published before. goal was obtain most satisfactory data provided in I. Some issues that mostly occurred as well having encountered. Nevertheless, general a measured points has obtained regardless those issues.
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ژورنال
عنوان ژورنال: Industrial & Engineering Chemistry Research
سال: 2021
ISSN: ['0888-5885', '1520-5045']
DOI: https://doi.org/10.1021/acs.iecr.1c01545